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Liu Shuangke

Liu Shuangke

National University of Defense Technology, China

Title: Graphene oxide coated S particles with long cycle life for lithium sulfur battery

Biography

Biography: Liu Shuangke

Abstract

Lithium sulfur battery has been regarded as one of the most promising high energy density rechargeable energy storage system for next generation due to its high theoretical specific capacity/energy density, natural abundance and environmental friendliness. However, the rapid capacity fade during long cycles which is caused by polysulfide shuttle and volume expansion during cycles tremendously inhibits its practical application. Building coated architecture of sulfur is one effective way to confine sulfur in the sulfur cathode thus enables stable cycle life. For example, Zhou et al. reported a sulfur/GO core-shell particle, in which sulfur particle were well wrapped by GO, demonstrating very stable cycle performance up to 1000 cycles. Herein, we also prepared GO-coated sulfur particles to enhance the cycle performance of lithium sulfur battery. Different from the above example which uses milled nano-sulfur particles, we use sodium sulfide and sodium sulfite to generate sulfur particles in aqueous GO solution followed by centrifugation and freeze-drying process, which results in in situ coating structure. The SEM (Fig. 1 a) and TEM (Fig. 1 b, c) images clearly demonstrate sulfur particles are well wrapped by wrinkled GO sheets, the high resolution TEM result indicate the crystal phase of sulfur particles. Due to the intact coating structure of GO and good chemical bond between sulfur and GO, the GO-coated sulfur particle cathode shows excellent cycling performance. Figure 1d demonstrates its cycle performance at 1 C rate, the initial discharge capacity is 513.4 mAhg-1, with 467.4 mAhg-1 retained after 400 cycles, corresponding to capacity retention of 91%. However, after 400 cycles, the capacity fades starts to speed up with 260.6 mAhg-1 and 225.1 mAhg-1 left after 800 and 1000 cycles. These results indicate that the physical GO coating could effectively suppress polysulfides shuttle effect and enhance the cycling performance but cannot completely eliminate it.

Figure 1: (a) SEM, (b) TEM, (c) high resolution TEM and (d) cycling performance at 1C rate of GO-coated S particles

Recent Publications:

1. Manthiram A, Fu Y, Chung S.H, Zu C, Su Y.S. Rechargeable Lithium-Sulfur Batteries, Chem. Rev. 2014, 114(23):11751-11787.

2. Wang D W, Zeng Q, Zhou G, Yin L, Li F, Cheng H M, Gentle I, Lu G. Carbon-sulfur composites for Li-S batteries: status and prospects. J. Mater. Chem. A, 2013, 1 (33): 9382~9394.

3. Rong J.P, Ge M.Y, Fang X, Zhou C.W. Solution Ionic Strength Engineering as a Generic Strategy to Coat Graphene Oxide (GO) on Various Functional Particles and Its Application in High-Performance Lithium-Sulfur (Li-S) Batteries, Nano Lett., 2014, 14,473-479.